Former AC Milan and Italy defender Maldini wants to return to the game but has ruled out working for any other Italian club.
"I've spoken to the [PSG] president several times," he said. "I've even been to see some of their games. But we've not managed to get to a genuine, precise offer."
Maldini, who won the Champions League five times as a player, said he believed it would be difficult for PSG to lift the trophy because of the nature of Ligue 1.
"PSG's problem is that they don't have matches with the same intensity that you get in the Champions League," he said.